The built-in and purchased games are enhanced versions which them easier to play (especially for new users that may not be familiar with the ZX Spectrum).
Normally the user is responsible for selecting the correct controls (Keyboard, Kempston, Interface II etc.) and pressing various keys to start the game (which vary from game to game).
Spectaculator automates all of this via a process known as Autoconfig: The correct controls are automatically selected and locked so the user doesn’t accidentally change them. Pressing the red button (or button A on a gamepad) starts the game.
However, if you want to use a Bluetooth keyboard to play these games, disable Autoconfig in the Settings section and reload the game – the controls will now be unlocked.